Tuning symmetry and magnetic blocking of an exchange-coupled lanthanide ion in isomeric, tetrametallic complexes: [LnCl6(TiCp2)3]
Chemical Science(2023)
Abstract
The synthesis and magnetic properties of two pairs of isomeric, exchange-coupled complexes, [LnCl6(TiCp2)3] (Ln = Gd, Tb), are reported. Magnetic exchange interactions and high local symmetry at the lanthanide ion are used to improve SMM behavior.
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Key words
tetrametallic complexes,lanthanide ion,magnetic blocking,exchange-coupled
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