Synthesis of P-stereogenic cyclicphosphinic amidesviaelectrochemically enabled cobalt-catalyzed enantioselective C–H annulation

Tao Liu,Wangqin Zhang,Chao Xu,Zhenhui Xu,Dingguo Song, Wei Qian,Gang Lu,Chang-Jun Zhang,Weihui Zhong,Fei Ling

Green Chemistry（2023）

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Abstract

We describe a cobalta-electro-catalyzed enantioselective C–H annulation of arylphosphinamides with alkynes for P-stereogenic compoundsviadesymmetrization and kinetic resolution processes.

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