Application of PLC-Based Spectrophotometric System Nitrogen Protection Device to Automated Direct Measurement of Target Substances in Zinc Hydrometallurgy

Due to the fast material reaction in zinc hydrometallurgy, the traditional national standard photometric method cannot capture the characteristic information of target substances in real time. Herein, a nitrogen protection device is built based on ultraviolet spectrophotometry, supplemented by a programmable logic controller (PLC), to form an automatic control system for the direct detection of target substances (SO42-, Pb2+ and S2-) in zinc hydrometallurgy. The baseline straightness comparison results show that the nitrogen atmosphere can effectively improve the stability of the instrument. Furthermore, the detection sensitivity of SO42-, Pb2+ and S2- under the nitrogen atmosphere is higher than that of the air atmosphere, manifesting in sensitivity increases of 16.23%, 18.05% and 17.91%, respectively. Additionally, devices based on PLC systems show advantages over manual control both in states feedback and information backtrack. Moreover, the regulation time and nitrogen consumption during the regulation process are reduced by 80% and 75%, respectively, which effectively reduces the test cost and improves the equipment utilization rate (from four cycles per day to six cycles per day). The device can meet the requirements of different target substances and different process conditions by changing the electronic control parts and air source, so it has great application potential in the automatic direct measurement of target substances in zinc hydrometallurgy.