Attempts to oxidize sulfides under mechanochemical conditions: synthetic and stereochemical aspects
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS(2023)
摘要
Preliminary experiments devoted to the reaction of model sulfides with several oxidation reagents under mechanochemical conditions are presented. No reaction with sodium metaperiodate and (−)-(8,8-dichlorocamphorylsulfonyl)oxaziridine was observed. An interesting selectivity was observed in the oxidation reaction of aryl trifluoromethyl sulfides with hydrogen peroxide in the presence of tungstic phosphoric acid as a catalyst. Asymmetric induction has been observed during the oxidation of methyl phenyl sulfide to the corresponding sulfoxide carried out in the presence of d-camphorsulfonic acid or beta-cyclodextrin.
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关键词
Mechanochemistry,sulfides,sulfoxides,sulfones,oxidation,asymmetric synthesis,selectivity
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