Synthesis of new ionic liquids based on (5Z,9Z)-alkadienoic acids and choline
MENDELEEV COMMUNICATIONS(2023)
摘要
Efficient synthesis of ionic liquids based on stereoisomerically pure natural and synthetic higher (5Z,9Z)-alkadienoic acids and choline hydroxide was developed. The key unsaturated carboxylic acids were prepared using the stereoselective cross-cyclomagnesiation reaction of aliphatic and oxygen -containing 1,2-dienes with EtMgBr in the presence of Mg metal and Cp2TiCl2 catalyst.
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关键词
new ionic liquids,ionic liquids,synthesis,acids
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