Assessing the reactivity of Fe(II) sorbed on smectite surface towards U(VI) reduction
JOURNAL OF MATERIALS RESEARCH(2023)
摘要
The reactivity of Fe(II) sorbed on clay edges towards U(VI) reduction is investigated at pH 6.0 using Fe-free synthetic montmorillonite (MONT), Fe-poor natural montmorillonite (Fe-MONT) and Fe-rich natural nontronite (NAu-2). Partial reduction of U(VI) by sorbed Fe(II) only occurred on MONT but neither on Fe-MONT nor NAu-2. In the former case, the formation of a hydrated uranyl silicate (soddyite)-like phase is demonstrated by U L III -edge EXAFS spectroscopy. 57 Fe Mössbauer spectrometry reveals that in this case 10% of the total sorbed Fe(II) was oxidized before- and an additional 6% after-addition of U(VI). The lack of reactivity towards U(VI) of Fe(II) sorbed on Fe-MONT or NAu-2 is likely due to inter-valence charge transfer (IVCT) between surface Fe(II) and structural Fe(III). The present study demonstrates that the reactivity of clay sorbed Fe 2+ towards U(VI) strongly depends on the nature of clay and correspondingly on the oxidation state of sorbed Fe. Graphical abstract
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关键词
Smectite clays,Sorption-reduction,Intervalence charge transfer
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