Papers Magnetic critical behavior and room temperature magnetocaloric effect in Ba1.9Pr0.1FeMoO6 double perovskite compound

MATERIALS RESEARCH BULLETIN(2023)

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摘要
In this paper, we report the critical behavior related to the magnetocaloric effect of Ba1.9Pr0.1FeMoO6 double perovskite. A maximum magnetic entropy change, |Delta S-M(max)| similar to 0.68 Jkg(-1)K(-1) and relative cooling power, RCP -62 Jkg(- 1) were observed under applied field of H = 2.5 T. The critical exponents were evaluated by using modified Arrott plots, Kouvel-Fisher, critical isotherm analysis and Widom scaling relation methods. A second order phase transition (paramagnetic to ferromagnetic) was observed at Curie temperature, T-C = 319.73 K with critical exponents beta = 0.45, gamma = 0.84, and delta = 2.91. The value of these critical exponents shows that this sample obeys mean field model and Widom scaling relation. Also, we observed that the different isothermal magneti-zation data are able to collapse into the two branches below and above TC based on the single scaling equa-tion M(H, epsilon) = epsilon(beta)f +/-(H /epsilon(beta+gamma)) that affirms the authenticity of the critical exponents.
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关键词
Magnetocaloric effect,Critical behavior,Double perovskite,Magnetization,XRD
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