Nickel-Catalyzed 1,1-Aminoborylation of Unactivated Terminal Alkenes
ACS CATALYSIS(2023)
摘要
Herein, we disclose a Ni-catalyzed 1,1-difunctionalization of unactivated terminal alkenes that enables the incorporation of two different heteroatom motifs across an olefin backbone, thus streamlining the access to alpha-aminoboronic acid derivatives from simple precursors. The method is characterized by its simplicity and generality across a wide number of coupling counterparts.
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关键词
nickel,unactivated alkenes,aminoborylation,chain walking,site selectivity
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