Unlocking the intrinsic mechanisms of A-site K/Na doped perovskite fluorides pseudocapacitive cathode materials for enhanced aqueous zinc-based batteries

Yi Li,Rui Ding,Ziyang Jia,Wujiang Yu,Ailin Wang,Miao Liu,Feng Yang,Yuzhen Zhang,Qi Fang,Miao Yan,Jinmei Xie,Xiujuan Sun,Enhui Liu

Energy Storage Materials（2023）

引用 6|浏览21

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摘要

•Proposing A-site K/Na doped Ni-Co-Zn-Mn ABF3 pseudocapacitive cathode.•Using K/Na-NCZMF electrode to construct aqueous zinc-based batteries (AZBs).•Clarifying intrinsic reasons for enhancement of A-site K/Na doping on ABF3 materials.•Elucidating charge storage mechanism of K/Na(3/1)-NCZMF electrode in alkaline media.

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关键词

Perovskite fluorides,A-site doping,Aqueous Zn-based batteries,Conversion pseudocapacitances,Density functional theory

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