Unlocking the intrinsic mechanisms of A-site K/Na doped perovskite fluorides pseudocapacitive cathode materials for enhanced aqueous zinc-based batteries
Energy Storage Materials(2023)
摘要
•Proposing A-site K/Na doped Ni-Co-Zn-Mn ABF3 pseudocapacitive cathode.•Using K/Na-NCZMF electrode to construct aqueous zinc-based batteries (AZBs).•Clarifying intrinsic reasons for enhancement of A-site K/Na doping on ABF3 materials.•Elucidating charge storage mechanism of K/Na(3/1)-NCZMF electrode in alkaline media.
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关键词
Perovskite fluorides,A-site doping,Aqueous Zn-based batteries,Conversion pseudocapacitances,Density functional theory
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