In-situ crystallization of lanthanide titanate stannate (Ln2TiSnO7) pyrochlore in glass: A glass-ceramic system for potential nuclear waste sequestration

Journal of Nuclear Materials(2023)

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摘要
•Lanthanide titanate stannate (Ln2TiSnO7) pyrochlore glass-ceramics are synthesized.•Cell parameters are in good agreement with the calculated data.•There is a linear relationship between Raman A1g peak position and Ln3+ionic radii.•Average pyrochlore grains are in submicron size.
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关键词
Glass-ceramics,Pyrochlore,Lanthanide titanate stannate,Ln2TiSnO7,Nuclear waste form
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