White light emission and energy transfer of LaMgAl11O19:Eu3+, Tb3+ phosphors
Luminescence : the journal of biological and chemical luminescence(2023)
Abstract
White-light-tunable LaMgAl11O19:x%Tb3+, y%Eu3+ series phosphors were prepared using the gel-combustion method. The structure and luminescence properties were studied, and the energy transfer of Eu3+ and Tb3+ in the LaMgAl11O19 system was also discussed. The results showed that the LaMgAl11O19 matrix exhibited strong emission in the blue-light region under the excitation of ultraviolet light, which resulted in conditions suitable for the preparation of white-light-tunable phosphors. The emission spectra of LaMgAl11O19:2%Tb3+, y%Eu3+ (y = 2%-9%) series phosphors were obtained through optimization experiments. It could be seen from the CIE diagram that by adjusting the doping quantities of Eu3+ and Tb3+ in the LaMgAl11O19 host, multicolor luminescence and white light emission in a single host could be achieved. By calculating the energy transfer efficiency and critical distance between Eu3+ and Tb3+ series phosphors, the mechanism of energy transfer between Tb3+ and Eu3+ was found to be the interaction between electric quadruples.
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Key words
Energy transfer,Eu3+, Tb3+,LaMgAl11O19,White light emission
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