Aminophosphine-substituted Fe/E (E = S, Se) carbonyls related to [FeFe]-hydrogenases: Synthesis, protonation, and electrocatalytic proton reduction

Shu-Fen Bai,Jun-Wei Ma,Ya-Nan Guo,Xiu-Mei Du,Yan-Lan Wang,Qian-Li Li,Shuang Lü

Journal of Molecular Structure（2023）

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摘要

•Four types of aminophosphine substituted Fe/E (E =S, Se) carbonyls were prepared.•All the compounds were well characterized and for some by X-ray crystallography.•Protonation of 2a by HBF4·Et2O afforded μ-hydride diiron complex 5.•Isomer transformation of 5ap-ba into 5ba-ba was observed.•Electrochemical and electrocatalytic properties of 1a-3a and 2e were investigated.

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关键词

Hydrogenase,Fe/E carbonyls,Aminophosphine,Protonation,Electrochemistry

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