Dual-lon Co-Intercalation Mechanism on a Na?V(6)0(16)-3H(2)O Cathode with a Commercial-Level Mass Loading for Aqueous Zinc-lon Batteries with High Areal Capacity br

A proton (H') and zinc ion (Zn-2) co-insertion model is put forward in this study to elucidate the capacity origin of an aqueous zinc ion battery (ZIB) based on a heavily loaded (similar to 15 mg cm) cathode, which consists of Na (2) VO6 3H(2) O (NVO) embedded particularly in the macropores of activated carbon cloth (ACC), coupled with a highly stable Zn/In anode. The confinement effect of these porous channels not only prevents the detachment of NVO from ACC but also well mitigates its volume change resulting from H' and Zn-2 co-intercalation, which collectively render the stability of NVO/ACC markedly enhanced. Moreover, the bicontinuous structure of NVO/ACC, as a result of the self-interlacing of intrapore NVO, which is first engineered into the nanobelts, and their interlocking with the carbon fibers of ACC, simultaneously giving rise to a solid and a holey framework, is favorable to the electron and ion transport throughout the entire electrode. The synergistic effect of such facile charge transfer kinetics and the high packing density of NVO in the cathode endows ZIBs with not only a good rate performance but also an exceptional areal capacity amounting to 4.6 mAh cm(3), far surpassing those reported for additional vanadium-based counterparts reported in the literature.