Exploring ligand substituent effects in stereoselective polymerization of racemic lactide using aluminium Salen-type complexes

Zengping Peng,Hassan Ahmed,Guangqiang Xu,Xuanhua Guo,Rulin Yang,Hongguang Sun,Qinggang Wang

Polymer Chemistry（2023）

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摘要

A number of unreported aluminium complexes bearing chiral cyclohexylsalen ligands were prepared and utilized for the asymmetric kinetic resolution polymerization (AKRP) of rac-lactide (LA). In this contribution, these chiral complexes...

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关键词

stereoselective polymerization,racemic lactide,ligand substituent effects,complexes,salen-type

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