Palladium-catalyzed allylic allenylation of homoallyl alcohols with propargylic carbonates
ORGANIC CHEMISTRY FRONTIERS(2023)
摘要
A palladium-catalyzed reaction of homoallyl alcohols with propargylic carbonates was realized via oxidative addition/decarboxylation/retro-allylation. The reaction proceeds with a wide substrate scope by using readily available starting materials, which provides a new and efficient method to synthesize a series of tri- and tetra-substituted allyl allenes.
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关键词
allylic allenylation,propargylic carbonates,homoallyl alcohols,palladium-catalyzed
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