Hydrogeochemical characterization of the alluvial aquifer of Catania Plain, Sicily (South Italy)

A hydrogeochemical study was carried out on the shallow Catania Plain alluvial aquifer, in eastern Sicily to reconstruct its hydrogeological structure, the meteoric recharge and to assess the influence of human activities on groundwater. To characterize the geochemistry of the shallow aquifer, two sampling campaigns were carried out, August–October 2004 and April–May 2005 in 47 sites distributed throughout the plain. The samples were collected and analyzed for physical–chemical parameters and major ions, as well as stable isotopes (δ 18 O and δ 2 H). Alluvial deposits with heterogeneous grain sizes constitute the aquifer. Varying conditions of vertical and horizontal permeability lead to the presence of a multilayered aquifer with different conditions of confinement and partial interconnection among layers. The sampled waters were separated into four groups of different compositions due to the water–rock interaction with the different lithologies present in and around the study area. Maps of electrical conductivity and sulfate show a systematic control of land use, in correspondence with the biggest farms. High sulfate concentration is due to both the natural interaction between local meteoric waters and Etna’s plume and the mixing with groundwater coming from the area where evaporitic rocks of the Gessoso Solfifera formation are present. In addition, anthropogenic contamination cannot be ruled out. A rain gauge network, consisting of 3 sites located at different altitudes, was installed to collect rain waters to determine isotopic data (δ 2 H and δ 18 O) and to measure the monthly rainfall amount. Based on the isotopic composition of sampled waters, it has been established that beyond the direct meteoric recharge, the recharging areas are in the North (Mt. Etna) and the South (Hyblean Plateau).