Nitrogen ligand influence on the CO-assisted ruthenium-catalyzed reductive amination
Mendeleev Communications（2023）
Abstract
A representative set of amines and N-heterocycles was applied as additives in the CO-assisted Ru-catalyzed reductive amination of p-anisaldehyde with p-anisidine. Among the tested ligands, pyridine caused a strong activation for low active aliphatic substrates while bidentate heterocyclic ligands possess significant inhibition of catalyst for the majority of substrates.
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Key words
ruthenium,nitrogen-containing ligands,reductive amination,amines,aldehydes,carbon monoxide,catalysis
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