Riverine inputs, spatiotemporal variations, and potential sources of phthalate esters transported into the Bohai Sea from an urban river in northern China.

The effects of anthropogenic activities on pollutant transport and inputs to the sea remain unclear. This study aimed to evaluate the impacts of sewage discharge and dam interception on riverine inputs, spatiotemporal variations, and potential sources of phthalate esters (PAEs) throughout the Haihe River, one of the largest rivers in northern China. Based on seasonal observations, the yearly inputs of the total concentrations of 24 PAE species (Σ24PAEs) from the Haihe River to the adjacent Bohai Sea were in the range of 5.28-19.52 tons, a considerable amount compared with those of other large rivers worldwide. The value of Σ24PAEs in the water column ranged from 1.17 to 15.46 μg/L and showed the following overall seasonal pattern: normal season > wet season > dry season, with dibutyl phthalate (DBP) (31.0 ± 11.9 %), di (2-ethylhexyl) phthalate (DEHP) (23.4 ± 14.1 %), and diisobutyl phthalate (DIBP) (17.2 ± 5.4 %) as the dominant components. Σ24PAEs were higher in the surface layer, slightly lower in the intermediate layer, and higher in the bottom layer. Σ24PAEs increased from the suburban section to the urban and industrial sections, which may indicate the effects of runoff, biodegradation, regional urbanization, and industrialization levels. The Erdaozha Dam intercepted 0.29-1.27 tons of Σ24PAEs inputs into the sea, but induced a substantial quantity accumulated behind the dam. The dominant sources of PAEs were the basic residential necessities (18.2-25.5 %) and industrial production (29.1-53.0 %). This study provides insights into the direct effects of sewage discharge and river dams on the inputs and variations in the PAEs entering the sea, which can be leveraged to manage and control PAEs in megacities.