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A new synthesis of D-lyxose from D-arabinose

Fa-Zhan Liang,Yu Chen,Xian-Hua Pan, Zheng Xia, Ding -Ding Yuan

CARBOHYDRATE RESEARCH（2023）

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Abstract
A new synthesis of rare D-lyxose from easily available D-arabinose is disclosed. The route includes 7 steps with a total 40% yield. Inversion of configuration at C3 promoted by DAST reagent is utilized on trans-2,3-di-hydroxy pentofuranose to provide cis-2,3-di-hydroxy pentofuranose, which is hardly synthesized using normal method.
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Key words
new synthesis,d-lyxose,d-arabinose
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