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Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations.

Moritz Nau,Larissa A Casper, Gernot Haug,Michael Linseis,Serhiy Demeshko,Rainer F Winter

DALTON TRANSACTIONS（2023）

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Abstract
Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing dimerization of the latter and of the one-electron reduced neutral radical.
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linker permethylation,foster valence tautomerism,thwart dimerization,ferrocenyl-triarylmethylium
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