Anion receptors with nitrone C-H hydrogen bond donors.
Chemical communications (Cambridge, England)(2023)
Abstract
We report the use of nitrone C-H groups as hydrogen bond donors for binding anions. Acyclic anion receptors with two nitrone moieties were synthesized by condensation reactions between aryl-aldehydes and -phenylenedihydroxylamines. The solid-state structure of dinitrones revealed C-H⋯O hydrogen bonds. Anion binding properties were investigated using NMR titration with halide and phosphate salts.
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Key words
receptors,hydrogen,bond
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