A Simple Way to Obtain a Decachloro Derivative of Cobalt Bis(dicarbollide)
REACTIONS（2023）
Abstract
A simple synthetic way to obtain a decachloro derivative of cobalt bis(dicarbollide) has been found. The reaction of cesium salt of cobalt bis(dicarbollide) anion with aluminum chloride in chloroform under reflux conditions results in Cs[3,3 '-Co(4,7,8,9,12-Cl5-1,2-C2B9H6)2] of high purity and good yield.
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Key words
carboranes,metallacarboranes,cobalt bis(dicarbollide),chlorinated derivatives
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