Cobalt‐Promoted Transfer Hydrogenation of Azaaryl Ketones by Using Formate as the Hydrogen Source
European Journal of Organic Chemistry（2023）
Abstract
A novel cobalt-catalyzed reduction of 2-pyridyl ketones and related heteroaryl compounds using formate as reductant was developed. Ketone substrate is activated by chelation with cobalt, which makes the present method highly selective. A possible reaction mechanism is proposed.
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Key words
alcohol,azaaryl ketone,cobalt,formate,transfer hydrogenation
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