Dispersing agglomerated Zn4In2S7 on g-C3N4 nanosheets to form a 2D/2D S-scheme heterojunction for highly selective photocatalytic cleavage of lignin models
CATALYSIS SCIENCE & TECHNOLOGY(2024)
Abstract
Lignin can be transformed into aromatic feedstock chemicals through photocatalysis, serving as an alternative to fossil resources, thereby meeting the growing demand for alternative energy resources. Herein, we introduce a unique 2D/2D S-scheme heterojunction photocatalyst, formed by uniformly dispersing agglomerated Zn4In2S7 on g-C3N4 nanosheets, designed to effectively cleave the C-beta-O bond in lignin under mild conditions. The formation of the S-scheme heterojunction notably separates and retains the strong photogenerated electrons and holes of the two photocatalysts, exhibiting excellent redox capabilities. Simultaneously, the two-step reaction mechanism of photocatalytic depolymerization of lignin was postulated to be oxidation followed by reduction through detailed mechanistic studies. Finally, a 99% conversion rate was achieved for the lignin model compound, with phenol and acetophenone being produced in yields of 87% and 86%, respectively, and maintaining strong depolymerization performance over four experimental cycles. This groundbreaking research offers a new idea for the design of photocatalysts to depolymerize lignin.
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