(LaCrO3) m /SrCrO3 superlattices as transparent p-type semiconductors with finite magnetization.

Nanoscale advances(2023)

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摘要
The electronic and magnetic properties of (LaCrO3) m /SrCrO3 superlattices are investigated using first principles calculations. We show that the magnetic moments in the two CrO2 layers sandwiching the SrO layer compensate each other for even m but give rise to a finite magnetization for odd m, which is explained by charge ordering with Cr3+ and Cr4+ ions arranged in a checkerboard pattern. The Cr4+ ions induce in-gap hole states at the interface, implying that the transparent superlattices are p-type semiconductors. The availability of transparent p-type semiconductors with finite magnetization enables the fabrication of transparent magnetic diodes and transistors, for example, with a multitude of potential technological applications.
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关键词
lacro<sub>3</sub><sub><i>m</i></sub>/srcro<sub>3</sub>,finite magnetization,p-type
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