COMPARATIVE XPS STUDY OF THE COMPOSITION AND ELECTRONIC STATE OF IRIDIUM IN BULK AND IMMOBILIZED BINUCLEAR [Ir(COD)Cl] 2 COMPLEXES

R. I. Kvon,A. V. Nartova,L. M. Kovtunova,V. I. Bukhtiyarov

Journal of Structural Chemistry（2023）

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摘要

Changes in the composition and electronic state of iridium in the [Ir(COD)Cl] 2 complex, which are induced by X-ray radiation and oxidation by atmospheric oxygen, are studied by XPS.

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关键词

X-ray photoelectron spectroscopy, metal organic iridium complex, single-site catalyst.

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