Ba4Ni3F14·H2O: a ferrimagnetic compound with a staircase kagomé lattice
Chemical communications (Cambridge, England)（2023）
Abstract
A new crystalline fluoride Ba4Ni3F14·H2O was found to exhibit a rare S = 1 staircase kagomé lattice built by Ni2+ ions. Magnetic measurements indicate a ferrimagnetic transition at ∼28 K, while 1/3 plateau can be observed from the magnetization curve. We suggest that the hydrogen-bond interactions of O-H⋯F pathways may play an important role for magnetic properties of the system.
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Key words
ferrimagnetic compound,kagomé
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