Deciphering the reaction mechanism and the reactivity of the TCEP species towards reduction of hexachloroiridate(IV)

Yanhong Shi,Hongwu Tian,Yanqing Xia,Ying Sun,Zongyi Zhou,Yanbiao Ren,Tiesheng Shi,Zhong Liu,Gang Ma

Journal of Molecular Liquids（2023）

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摘要

•The oxidation of TCEP by [IrCl6]2− has been investigated kinetically over a wide pH range.•Observed second-order rate constant vs pH profile has been established.•Reaction mechanism involving phosphine radical cations is proposed and convincing.•The reactivity of the TCEP species towards an oxidant is deciphered for the first time.

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关键词

Tris(2-carboxyethyl)phosphine,Hexachloroiridate(IV),Kinetic analysis,Mechanism

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