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Can ionic liquids exist in the soil environment? Effect of quaternary ammonium cations on glyphosate sorption, mobility and toxicity in the selected herbicidal ionic liquids

Anna Parus,Oskar Zdebelak,Tomasz Ciesielski,Radosław Szumski,Marta Woźniak-Karczewska,Grzegorz Framski,Daniel Baranowski,Michał Niemczak,Joanna Zembrzuska,Tomáš Cajthaml,Hermann J. Heipieper,Łukasz Chrzanowski

Journal of Molecular Liquids（2023）

Cited 4|Views11
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Abstract
•Verification of cation–anion interactions of ionic liquids in the environment.•No ionic pair formation confirmed by 2D NMR for the defined ionic liquid.•Independent cation and anion sorption in soil.•Ionic liquids do not form a stable ion pair in the environment.•Ionic liquids are not a new type of contaminant in the environment.
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Key words
Ionic bond energy,Ion integrity,Phytotoxicity,Sorption isotherm,Synthesis,Toxicity
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