Rotational and deperturbation analysis of the interacting A2Π1/2, v = 11 ∼ B2Σ+, v = 6 states of yttrium monoxide (YO) molecule
Journal of Quantitative Spectroscopy and Radiative Transfer（2023）
Abstract
•Analysis of the jet-cooled spectra of the A2Π1/2 v=11-13 and B2Σ+ v=5-6 states from the X2Σ+ state•Deperturbation of A2Π1/2 v=11∼B2Σ+ v=6 pair of state with spin-orbit, L-uncouple interactions•Vibronic band intensity ratio in agreement with mixing coefficient from depertubation analysis•A2Π1/2 state in v=12 and 13 vibrations found unperturbed contrary to the earlier observation
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Key words
Yttrium monoxide molecule,Gas-phase spectra,Molecular constants,Laser-induced and dispersed fluorescence,Rovibronic spectra,Deperturbation analysis
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