Synergistic catalysis of hypercrosslinked ionic polymers with multi-ionic sites for conversion of CO2 to cyclic carbonates

Xu Liao,Zeyu Wang,Lingzheng Kong,Xilin Gao,Jiao He,Dongha Huang,Jinqing Lin

Molecular Catalysis（2023）

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摘要

•The metal-free HIPs catalysts with multi-ionic sites, high ionic density and hydrogen bond donors were synthesized.•The introduction of HIPs with multi-ionic sites has a synergistic effect on the improvement of catalytic performance for CO2 cycloaddition reaction.•The catalyst HBIM(0.5)@QA-Br exhibited excellent catalytic activity for cycloaddition of CO2 with epoxides at atmospheric pressure in the short reaction time.

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关键词

CO2 cycloaddition,Hypercrosslinked ionic polymers,Multi-ionic sites,Synergistic catalysis

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