Allylsulfones through Palladium-Catalyzed Allylic C-H Sulfonylation of Terminal Alkenes

Tingting Chen, Jassmin Lahbi,Gianluigi Broggini,Alexandre Pradal,Giovanni Poli

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY（2023）

引用 2|浏览3

暂无评分

摘要

Two previously unknown protocols for Pd-catalyzed allylic C-H sulfonylation of terminal alkenes have been developed. While the former consists of a direct Pd(II)-catalyzed oxidative C-H allylic sulfonylation in the presence of sulfinate anions, the latter involves a sequential one-pot Pd(II)-catalyzed C-H allylic acetoxylation followed by a Pd(0)-catalyzed sulfonylation. The scope of both protocols was studied on 25 examples.

查看译文

关键词

allylsulfones,C-H activation,one-pot sequential reactions,palladium catalysis,sulfonylation

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要