Bis(1-naphthylimino)acenaphthene: Redox Properties and One-Electron Reduction
DOKLADY PHYSICAL CHEMISTRY(2023)
Abstract
Redox properties of bis(1-naphtylimino)acenaphthene have been studied using various voltammetry techniques. Radical anion of diimine ligand has been obtained in situ through electrochemical reduction, and its optical properties have been studied. A new sodium complex having the anion-radical form of bis(1-naphthylimino)-acenaphthene has been obtained and structurally characterized. We have found that the solvent nature affects the long-wavelength absorption band of the sodium complex, which is determined by the contribution of the coordinated solvent molecules to the lowest unoccupied molecular orbital (LUMO) energy.
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Key words
radical,bis(imino)acenaphthene,redox properties,spectroelectrochemistry,sodium complex
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