Triggering reversible anion redox chemistry in O3-type cathodes by tuning Na/Mn anti-site defects
ENERGY & ENVIRONMENTAL SCIENCE(2023)
摘要
Oxygen anion redox (OAR) plays a crucial role in the capacity and stability of oxide cathodes in sodium-ion batteries but the intrinsic mechanism is poorly understood. How to trigger and stabilize OAR is challenging, particularly for O3-type transition metal (TM) oxide cathodes. Herein, we clarify that Na/Mn anti-site defects mainly trigger OAR in the O3-NaMn1/3Fe1/3Ni1/3O2 cathode, and OAR activity and reversibility can be enhanced by tuning Na/Mn anti-site defects with Ho doping. Replacing the Fe3+ site by Ho3+ promotes more Na/Mn anti-site defects, enabling more O lone-pair electrons to participate in charge compensation. Meanwhile, Ho3+ enlarges the O-O bond and angle O-TM-O angle, and maintains the single-electron oxygen hole configuration of (O-)-TM-(O-) and inhibits O-O shortening caused by electron loss, avoiding forming an (O-2)(2-) dimer. Furthermore, Ho3+ induces the splitting of the TM 3d orbital energy band above the Fermi level and generates low energy orbitals of Mn e(g)* and Ni e(g)*, which promotes the transition of O lone-pair electrons and Ni e(g)* orbital electrons, and simultaneously activates the redox activity of anions and cations. After regulation, the capacity increases from 146.8 to 184.9 mA h g(-1) and the capacity retention increases from 40.3 to 90.0%. This study reveals the OAR mechanism in the O3-type cathode and presents insights into how to trigger and stabilize OAR.
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关键词
redox chemistry,reversible anion,anti-site
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