Total Synthesis of (E/Z) des-Hydroxy Triticone A and B

Sunil Dattatray Chakave,Shrikant Shete, Sandeep Reddy Kandukuri,Mark Montgomery,Bhanu N. Manjunath,Ravindra Punjaji Sonawane

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY（2023）

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摘要

The first total synthesis of des-hydroxy triticone A and B was achieved in 12 steps. The highly chemoselective, base mediated iodolactamization of olefins with N-OMe amide motif is a key highlight of the synthesis.

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关键词

crop protection,iodolactamization,natural products,spirocycles,triticones

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