Cr-promoted formation of B2+L2 1 composite nanoprecipitates and enhanced mechanical properties in ferritic alloy

The critical role of Cr on nanoprecipitates and the mechanical property of Fe-Ni-Al-Mn ferritic steel were systematically studied in this research. The two types of nanoprecipitates in the Cr added alloy were characterized through a combination of aberration-corrected scanning transmission electron microscopy and atom probe tomography techniques. The atomic-scale structure and chemistry analysis reveal that fine globular-shaped precipitates have a B2-structure, while coarse elongated precipitates have B2 + L2 1 composite structures. The first-principles calculations reveal that the segregation of Cr at the L2 1 /bcc interface reduces the interface and strain energy for the nucleation of the L2 1 -type phase. With the increasing precipitate size, the B2 structure is gradually transformed to L2 1 to reduce elastic strain, thereby promoting the formation of B2 + L2 1 composite nanoprecipitate. The addition of 10 wt% Cr results in an increase of similar to 275 MPa in yield strength without obvious loss of ductility. The effect of Cr on the strength mechanisms were quantitatively analyzed, revealing that the strength of the ferritic alloy mainly improved by the formation of B2 + L2 1 composite nanoprecipitate, which is more effective than solid solution strengthening. (c) 2022 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.