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TBHP/KI-Promoted Oxidative Cyclization of alpha-Aminoketones for One-Pot Synthesis of Substituted 2-Acyloxazoles

Jiecheng Zheng,Dali Zhu,Zhangyou Yang,Huali Chen,Wei Wang,Lin Ling Gan,Zongjie Gan

SYNTHESIS-STUTTGART（2023）

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Abstract
A metal-free and facile synthesis of substituted 2-acyloxazole derivatives from alpha-aminoketones was developed via a TBHP/KI-promoted oxidative cyclization. This procedure proceeded smoothly under mild conditions and a broad scope of 2-acyloxazoles were obtained in moderate to good yields.
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Key words
metal-free,TBHP/KI,2-acyloxazole,oxidative cyclization
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