Iron doped BiOBr loaded on carbon spheres for improved visible-light-driven detoxification of 2-chloroethyl sulfide.

In this study, flower-like porous iron doped bismuth oxybromide on porous activated carbon visible light catalysts (BiOBr/Fe@AC) were prepared by a reactive imidazole ionic liquid surfactant assisted solvothermal process. The morphologies, structures, optical properties and photocatalytic properties were investigated in detail. The morphology of the synthesized Fe doped BiOBr composites gradually changed from a regular spherical shape to a non-specific shape with the increase of the alkyl chain length of the ionic liquid surfactants. The photocurrent of BiOBr/Fe@AC composites is greatly influenced by the content of Fe, the type of carbon sphere and the size of the composites. The photocatalytic activity of the obtained BiOBr/Fe@AC composites was evaluated by the degradation of 2-chloroethyl sulfide (CEES) under visible light. The BiOBr/Fe@AC composites exhibited significantly enhanced photocatalytic performance compared to that of pure BiOBr and the 10.0% Fe doped BiOBr/Fe@AC composite displayed the highest photocatalytic activity. The main active species were determined to be holes and superoxide radicals by electron spin resonance (ESR) analysis and free radical trapping experiments. The introduction of iron can improve the separation and transfer rate of photoinduced charges. Carbon spheres can enhance light harvesting, improve electron transfer and increase the number of catalytic active sites. Iron and carbon embellishment is an effective strategy to enhance the photocatalytic efficiency of BiOBr. Finally, a possible photocatalytic mechanism of BiOBr/Fe@AC has been proposed.