Effect of cyclodextrins inclusion complexes into absorption and emission spectra of P-methylaminobenzoate derivatives: A DFT and TD-DFT investigation

Journal of fluorescence(2023)

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摘要
In this study, density functional theory (DFT) and time-dependent DFT (TD-DFT) studies of methyl 4-aminobenzoate and methyl 4- amino-2-hydroxybenzoate and their inclusions complexes with α and γ-cyclodextrins were applied to control the effect of cyclodextrins on the absorption and emission properties of P-methylaminobenzoate derivatives. Absorption and emission spectra of free and encapsulated P-methylaminobenzoate derivatives were successfully analysed and compared with experimental results. Interestingly, conformational changes between ground and excited states of both fluorophores were also studied. Graphical Abstract
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关键词
Absorption and emission,B3LYP-D3/ cc-pVDZ,P-methylaminobenzoate derivatives,TD-DFT/B3LYP/6-31G(d),α and γ-CDs
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