Selective Fluorosulfonylation of Thianthrenium Salts Enabled by Electrochemistry

Xianqiang Kong,Yiyi Chen, Qianwen Liu, WenJie Wang, Shuangquan Zhang,Qian Zhang,Xiaohui Chen,Yuan-Qing Xu,Zhong-Yan Cao

Organic Letters（2023）

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摘要

A practical electrochemically driven method for fluorosulfonylation of both aryl and alkyl thianthrenium salts has been disclosed. The strategy does not need external redox reagents or metal catalysts. In combination with C–H thianthrenation of aromatics, this method provides a new tool for the site-selective fluorosulfonylation of drugs.

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关键词

thianthrenium salts,selective fluorosulfonylation

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