Treatment of industrial ferric sludge through a facile acid-assisted hydrothermal reaction: Focusing on dry mass reduction and hydrochar recyclability performance

Large amounts of Fenton sludge and waste activated sludge (WAS) are mixed as ferric sludge (FS) in most industrial wastewater treatment plants. The treatment of such waste represents a challenge and quantity-dependent cost, so that a reliable way for FS waste reduction is required. In this study, we develop a facile acid-assisted hydrothermal treatment (HT) for the cost-efficient treatment of hazardous FS waste. Sulfuric acid was dosed at 0.25 mL/g dry solid (DS) to the HT process, which significantly increased the total solid mass reduction (TMR) by 25.1 % and dry mass reduction (DMR) by 104.4 %. The participation of sulfuric acid during the HT process changed the HT reaction pathway from dehydration to demethylation based on the analysis of the derivative thermogravimetric and Van Krevelen diagram. The addition of sulfuric acid improved the release of Fe from FS by 52.9 %, which contributed to the DMR. During the acid-assisted HT, Fe(III) was effectively reduced to Fe(II) within the produced hydrochar, which can be recycled for the Fenton reaction during the degradation of actual industrial wastewater such as pharma- ceutical wastewater. Moreover, Sulfuric acid facilitated the generation of sulfonated hydrochar, which was efficient as an adsorbent for the complete removal of some metals such as Cu(II) - cation metal (98.8 %) and Cr(VI) - anion metal (99.9 %). This study firstly provides a novel and reliable approach for hazardous FS reduction and pointed out the recycling of hydrochar as the supplement for the Fenton reaction and adsorbents for some hazardous heavy metals.