HTE and machine learning-assisted development of iridium(I)-catalyzed selective O–H bond insertion reactions toward carboxymethyl ketones

Yougen Xu, Feixiao Ren,Lebin Su,Zhaoping Xiong, Xinwei Zhu,Xinyuan Lin,Nan Qiao, Hao Tian, Changen Tian,Kuangbiao Liao

Organic Chemistry Frontiers（2023）

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摘要

Functional group substituted carboxymethyl ketones, especially heterocyclic ones, are important structural motifs for biologically active molecules, but their synthesis is challenging. In this work, by combining HTE and machine learning...

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关键词

reactions,ketones,learning-assisted

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