Extending the Hammett correlation to mechanochemical reactions.
Chemical communications (Cambridge, England)（2023）
Abstract
Using Raman monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical-organic chemistry could be transferable to ball milling reactions in the solid state.
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Key words
mechanochemical reactions,hammett correlation
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