Molecular Sn(II) precursors for room temperature deposition of crystalline elemental tin.
Dalton transactions (Cambridge, England : 2003)(2023)
摘要
We report mild routes for the deposition of crystalline films of elemental tin the formation and subsequent decomposition of unstable tin(II) hydrides. Specifically, we take advantage of efficient OBu/H metathesis involving Sn(II) alkoxide precursors and the hydride source pinacolborane (HBpin); related -N(SiMe)/H exchange also afforded elemental tin as a final (insoluble) product.
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