The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts.
Chemical communications (Cambridge, England)(2023)
摘要
The molecular-level role of alkoxide salts, used as alternative additive to -methylpyrrolidone in iron-catalyzed alkyl-alkenyl/aryl cross-coupling reactions, is investigated. Detailed spectroscopic studies reveal that alkoxides promote the formation of homoleptic organoferrates such as [FeMe], providing an alternative to toxic NMP to access these reactive intermediates.
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关键词
alkoxide additives,molecular-level,iron-catalyzed,cross-coupling
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