Signatures of Urbanization in Temperate Highland Peat Swamps on Sandstone (THPSS) of the Blue Mountains World Heritage Area

Urban freshwater ecosystems exhibit distinct patterns of elevated major ions (calcium, potassium and bicarbonate) and metals, referred to as the 'urban geochemical signature'. However, the implications of this urban fingerprint at the water-sediment interface within sensitive freshwater systems are not well-known. Temperate Highland Peat Swamps on Sandstone are unique freshwater wetlands found within and surrounding the high-conservation value Greater Blue Mountains World Heritage Area and are a listed 'endangered ecological community' in Australia. Water and sediment chemistry were assessed within four urban and four naturally vegetated swamp catchments, through field monitoring and novel laboratory techniques (including X-ray diffraction). Urban swamps had distinct elemental signatures compared to naturally vegetated swamps. Urban swamp water displayed increased pH, elevated ionic strength, major ions (calcium and bicarbonate) and metals (strontium, barium, manganese and iron). Urban swamp sediment had higher calcium, with calcium hydroxide detected at two urban sites. Urban development and concrete drainage infrastructure in swamp catchments modify natural hydrology and water chemistry. Findings suggest swamp sediments may act as sinks of metals and alkalinity, with urbanization remaining a potential source. However, the consequences for high-conservation value systems are not well understood. As urbanization continues to expand, this has implications for fragile freshwater environments worldwide.