Oxidative addition of 8-bromo-9-ethyl-1,N6-ethenoadenine to d10 metals

Mareike C. Jahnke,Soham Mandal,Florian Kampert,Tristan T.Y. Tan,Jens Müller,F. Ekkehardt Hahn

Inorganica Chimica Acta（2023）

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摘要

The adenine derivative 8-bromo-9-ethyl-1,N6-ethenoadenine 3 has been synthesized and oxidatively added to [M0(PPh3)4] (M = Pd, Pt). Depending on the procedure for the protonation as well as the metal, either the mononuclear complexes trans-[4]BF4 and trans-[5]BF4 or the dinuclear complex [6](BF4)2 were obtained.

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关键词

Protic N-Heterocyclic Carbene,Oxidative Addition,Palladium,Platinum,Adenine

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