catena-[[(nitrato-κO)silver(I)]-μ-1,10-phenanthroline-5,6-dione-κ4O,O′:N,N′]

In the title one-dimensional coordination polymer, [Ag(NO3)(C12H6N2O2)]n, the AgI atom is pentacoordinated by two N atoms from a 1,10-phenanthroline-5,6-dione (phen-dione) ligand, one O atom from the nitrate anion and two O atoms from another phen-dione ligand. The coordination environment around silver is slightly distorted square-pyramidal. Interestingly, the Ag—O distances to the phen-dione ligand are different [Ag—O = 2.612 (6) and 2.470 (5) Å]. The one-dimensional chains run parallel to [101] and are further interconnected by weak hydrogen bonds (C—H...O) and π–π stacking interactions [centroid–centroid distances 3.950 (4) and 3.792 (4) Å], forming a three-dimensional supramolecular network.