Dichlorido[6,8,22,24,34,36-hexamethyl-33,35-diaza-3,11,19,27-tetraazoniapentacyclo[27.3.1.15,9.113,17.121,25]hexatriaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodecaene-κ6N3,N11,N19,N27,N33,N35]dipalladium(II) bis(perchlorate) N,N-dimethylformamide disolvate methanol disolvate

In the crystal structure of the title compound, [Pd2(C36H42N6)Cl2](ClO4)2·2C3H7NO·2CH3OH, the dinuclear PdII complex cation lies on an inversion center. Each PdII ion has a distorted square-planar coordination sphere, defined by three N atoms of the macrocyclic ligand and a chloride ion. The PdII complex cations and the methanol molecules are linked through N—H...O and O—H...O hydrogen bonds, forming a zigzag chain along [101]. An intramolecular N—H...Cl hydrogen bond is also observed.