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Synthesis of (+)-(R)-Tiruchanduramine

Zahraa S. Al-Taie,Barbara Bartholomew,Christopher Cartmell,Richard T. Froom,Russell G. Kerr,Rolf Kraehenbuehl,Patrick J. Murphy,Robert J. Nash,Yana B. Penkova,Alexander van Teijlingen

Molecules（2022）

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Abstract
The absolute stereochemistry of the marine alkaloid (+)-(R)-tiruchanduramine was established via a convergent total synthesis in six steps and 15.5% overall yield from Fmoc-D-Dab(Boc)-OH.
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<i>Synoicum macroglossum</i>,tiruchanduramine,β-carboline,guanidines
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